|
|
Determination of toxic elements in wines
Hajdučková, Iva ; Vespalcová, Milena (referee) ; Diviš, Pavel (advisor)
The aim of this study was to determine the occurrence of selected toxic elements in wine. The theoretical part described technology of wine production and selected toxic elements (cadmium, lead, copper, zinc, nickel and chromium) in the terms of their impact on wine quality and their effects on the human organism. It provides an overview of instrumental analytical methods, which can be used for the analysis of toxic metals. In the experimental part inductively coupled mass spektrometry technique was used for the analysis of wine samples. The measured values are statistically processed and compared with current legislation.
|
|
| |
|
|
Selected inorganic pollutants in foodstuffs
Kroupová, Kateřina ; Vítová, Eva (referee) ; Vitoulová, Eva (advisor)
This bachelor thesis is focus on occurrence of inorganic pollutants in foodstuffs. The introduction is dedicated to apperance of individual selected elements in foodstuffs. Concentration of these elements is very important factor for examination of toxic effects for the human organism. If we want to avoid the harmful effects to the human organism, we have to define border limits. Work is based on the legislative of Czech republic. Second part of this study is focused on the biological monitoring. The biological monitoring is important for precautionary measures. In the third part of this study are described toxical effects of these elements to the human organism. Before qualitative and quantitative analysis by instrumental techniques is important to properly take the sample. In the fourth and fifth part of this work are mentioned methods used for determination of these elements and metods of taking samples. This bachelor thesis provide complex view on the problems of pollutants in foodstuffs and it should be used as a base for following diploma thesis.
|
|
| |
|
|
The influence of evapotranspiration on the groundwater of floodplain forests: Libický luh
Vašková, Hana ; Weiss, Tomáš (advisor) ; Slavík, Martin (referee)
The recherche part of this bachelor thesis deals with evapotranspiration from floodplain forests and its influence on the depth of the groundwater level and mineralization of groundwater. As floodplain forests in the Czech Republic are represented only in smaller fragments, there is a mention of the effect of mineralization on plants. The thesis describes the principle and use of stable isotopes in hydrogeology and the comprehensive characteristics of the area of interest of the experimental part, the Libický luh National Nature Reserve. The experimental part includes the observation of the level, conductivity, temperature, pH, and determination of the isotopic composition of the underground and surface water in Libický luh, where high mineralization of the groundwater was previously detected. The thesis discusses the effect of evapotranspiration on the content of dissolved substances in the water in Libický luh as a possible cause of this phenomenon. It was found that as the temperature rises, the groundwater level drops, and that mineralization remains relatively constant throughout the year. The drop in the groundwater level is evidently caused by intensive evapotranspiration from the floodplain forest during the growing season. However, longer time series of conductivity or hydrochemical...
|
|
|
Application of Atomic Absorption Spectrometry for Determination of Selected Elements from Potential Ecological Burden Area
Juránková, Lada ; Hraníček, Jakub (advisor) ; Šíma, Jan (referee)
This work is focused on the determination of selected (chemical) elements (Fe, Mn, Zn, Cr, Na, K, Mg a Ca) in a potential ecological burden area using flame atomic absorption spectrometry as a detection technique. A potential ecological burden is represented by tires which are used as a construction material or as an environment surrounding for growing decorative and consumable plants. Analytes were determined in plant origin samples. Firstly, the samples were dried in a laboratory electric dryer. The weighted amount of a dried sample (approximately 0.2 g) was digested inside a microwave decomposition device with an addition of nitric acid and hydrogen peroxide. An optimization of experimental parameters was done for each of the elements before sample measuring. A burner height was optimized and 8 mm height was chosen as a optimum for most elements. Under the optimum condition basic characteristics were measured for each element separately. These characteristics included limits of detection that were: 0.05; 0.01; 0.08; 0.21; 0.02; 0.01; 0.01; 0.01 mg L-1 for the following elements: Fe, Mn, Zn, Cr, K, Ca, Mg and Na, respectively. The limits of quantification, sensitivity and repeatability were determined for each element as well. A significant attention was paid to the content of zinc in the studied...
|
|
|
Underground waters and springs at Jeseník Spa: New hydrogeochemical data
Kohn, Tomáš ; Goliáš, Viktor (advisor) ; Vylita, Tomáš (referee)
This thesis deals with the areal survey of water resources in the area of Priessnitz baths, to search for natural medicinal sources and advanced data collection for evaluation radiohydrogeochemical situation of the area. The area of interest is situated in the Hrubý Jeseník mountains. Hydrogeologically it is a hard rock, which consists mainly of metamorphic rocks of the Bohemian Massif, the Moravian-Silesian region, presented as the methamorfic envelope of the desen group of Silenics. Altogether, 83 objects were recorded and many of them were visited repeatedly. Physical parameters (temperature, pH, Eh, conductivity), activity 222Rn and flow rate were measured. In addition, the chemical composition and tritium contents were determined on selected sources. Conductometry, thermometry, and probes for peloids were conducted. There was no source of water (or peloid) that would reach the criteria of a natural healing source (according to the Czech spa law). However, the overall hydrogeological and hydrochemical situation is quite complicated. Both the genesis of water and its chemical composition is highly heterogeneous and influenced by the heterogenical geological structure. Generally, we have distinguished three types of water according to the chemical composition. We also divided the water sources...
|
|
|
Mineral waters in the Bad Brambach - Skalná area, the current knowledges.
Turnová, Štěpánka ; Goliáš, Viktor (advisor) ; Hrkal, Zbyněk (referee)
This paper summarizes the findings of the mineral waters around Skalná - Bad Brambach. Bad Brambach are radon spa that work here since 1912. Source Wettinquelle is one of the strongest radon springs in the world. Around Skalná is anomalous quantities of uranium, however, that there occurs in such small particles that netěžitelné. Radon is a decay product of U238 series. Within the study area is also NPR Soos, who is known moffetes, but there also are so-called diatomaceous peak which is a dry salt lake containing diatoms. Area of the Nový Kostel is the area with the most frequent occurrence of earthquakes in the Czech Republic. Several earthquake swarms were recorded as well as the local populations. Recent earthquake activity has been recorded in 2011. There are also several other spa municipal Františkovy lázně, Mariánske lázně, Karlovy Vary and other radon baths, which already are but a little further, Jáchymov.
|
|
|
Age estimation in two recent European population by assessment of permanent tooth mineralization
Černá, Magdaléna ; Velemínská, Jana (advisor) ; Stránská, Petra (referee)
Age estimation is a common requirement in forensic, bioarcheological and biomedical practice. This master thesis deals with age estimation based on permanent tooth mineralization according to Demirjian et al. (1973). The research material consisted of orthopantomograms of 716 Czech and 743 French children aged between 4 and 15 years. The purpose of this study was to analyse the suitability of the original French-Canadian standards for age estimation (Demirjian a Goldstein, 1976) and the recent Belgian standards (Willems et al., 2001) in Czech and French population. Another aim of the study was to evaluate the accuracy of the neural network method that represents a completely new approach in data prediction. In order to express the accuracy of estimate we used mean and median of difference between chronological and dental age, and RMS error. Using logistic regression, differences in tooth mineralization between Czech and French population and between girls and boys were also evaluated. Our results indicate that the French-Canadian standards gave a consistent overestimation of dental age compared with chronological age. Mean difference was 0,33 years for Czech children and 0,45 and 0,46 years for French girls and boys, respectively. We found that Willem's method and neural network method were more...
|
|
|
Application of Atomic Absorption Spectrometry for Determination of Selected Elements from Potential Ecological Burden Area
Juránková, Lada ; Hraníček, Jakub (advisor) ; Šíma, Jan (referee)
This work is focused on the determination of selected (chemical) elements (Fe, Mn, Zn, Cr, Na, K, Mg a Ca) in a potential ecological burden area using flame atomic absorption spectrometry as a detection technique. A potential ecological burden is represented by tires which are used as a construction material or as an environment surrounding for growing decorative and consumable plants. Analytes were determined in plant origin samples. Firstly, the samples were dried in a laboratory electric dryer. The weighted amount of a dried sample (approximately 0.2 g) was digested inside a microwave decomposition device with an addition of nitric acid and hydrogen peroxide. An optimization of experimental parameters was done for each of the elements before sample measuring. A burner height was optimized and 8 mm height was chosen as a optimum for most elements. Under the optimum condition basic characteristics were measured for each element separately. These characteristics included limits of detection that were: 0.05; 0.01; 0.08; 0.21; 0.02; 0.01; 0.01; 0.01 mg L-1 for the following elements: Fe, Mn, Zn, Cr, K, Ca, Mg and Na, respectively. The limits of quantification, sensitivity and repeatability were determined for each element as well. A significant attention was paid to the content of zinc in the studied...
|
guest ::
